Vol. 1, Issue 3 (2013)
Studies of Some Physicochemical Properties of Isatin
Author(s): Shipra Baluja*, Kapil Bhesaniya, Ritesh Vithalani, Falguni Karia
Abstract: Some physicochemical properties such as dissociation constant, acoustical parameters and thermal studies of isatin have been studied in methanol and 1,4-dioxane at 298.15 K. It is observed that pKH value is slightly greater in methanol + water system. Acoustical properties have been evaluated from experimental data of density, viscosity and ultrasonic velocity. It is observed that in both the solvents, strong solute-solvent interactions exist for isatin. Further, degradation is single step process.
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![The plot of pH against volume of NaOH in [A] methanol + water and [B] 1,4-dioxane + water at 298.15K.](https://www.chemijournal.com/up/graphics/30/19.1.jpg)
Fig. 1: The plot of pH against volume of NaOH in [A] methanol + water and [B] 1,4-dioxane + water at 298.15K.
![The variation of velocity (U) with concentration for Isatin in [A] methanol and [B] 1,4-dioxane.](https://www.chemijournal.com/up/graphics/30/19.2.jpg)
Fig. 2: The variation of velocity (U) with concentration for Isatin in [A] methanol and [B] 1,4-dioxane.
![The variation of intermolecular free path length (Lf) against concentration for Isatin in [A] Methanol and [B] 1,4-dioxane.](https://www.chemijournal.com/up/graphics/30/19.3.jpg)
Fig. 3: The variation of intermolecular free path length (Lf) against concentration for Isatin in [A] Methanol and [B] 1,4-dioxane.
Pages: 93-100 | 1814 Views 104 Downloads
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How to cite this article:
Shipra Baluja*, Kapil Bhesaniya, Ritesh Vithalani, Falguni Karia. Studies of Some Physicochemical Properties of Isatin. Int J Chem Stud 2013;1(3):93-100.
