International Journal of Chemical Studies
  • Printed Journal
  • Indexed Journal
  • Refereed Journal
  • Peer Reviewed Journal
P-ISSN: 2349-8528, E-ISSN: 2321-4902   |   Impact Factor: GIF: 0.565 NAAS Rating: 5.31 NEW

International Journal of Chemical Studies

Vol. 5, Issue 3 (2017)
Spectroscopic and elemental analysis studies of the reactions of triiodomethane with dialkyl and alkylenedithiophosphate Salts and acids


Author(s): Adnan Elkhaldy and Alaa M Abu Shanab

Abstract: Methyl tris-dialkyl and alkylenedithiophosphates, HC[S2P(OR)2]3 where R = Et, n-Pr, i-Pr, i-Bu and Ph and HC[S2POGO]3, where G = -CMe2, CMe2, -, CH2CMe2CH2-, and -CH2CEt2CH2-, have been synthesized for the first time by the reactions of iodoform with the alkali metal salt of the corresponding ligand in anhydrous toluene in 1:3 molar ratio respectively. These compounds are powdery solids or viscous liquids and are soluble in common organic solvents, in which they show monomeric behavior. Based on elemental analyses, molecular weight determinations, IR and NMR (1H and 31P) spectral data, chelate tetrahedral structures have been proposed for these derivatives

Pages: 310-313  |  648 Views  17 Downloads

download (2810KB)
How to cite this article:
Adnan Elkhaldy, Alaa M Abu Shanab. Spectroscopic and elemental analysis studies of the reactions of triiodomethane with dialkyl and alkylenedithiophosphate Salts and acids. Int J Chem Stud 2017;5(3):310-313.
International Journal of Chemical Studies