Vol. 5, Issue 2 (2017)
Synthesis of biaryls through electron-transfer oxidation of Organo-Cuprates with Benzil
Author(s): M Jalilur Rahman, Manjur Alahy, Md. Abdul Malek, Sadia Jannat, Rehana Pervin and Shameem Ara Begum
Abstract: A new method for the homo-coupling of aryl halides via electron-transfer oxidation of organo-cuprate Ar2Cu(I)(MgBr)2 with benzil (a 1,2-diketone) is disclosed. Various organo-cuprates were prepared from arylmagnesium bromide and half-equivalent of CuI in dry THF under nitrogen. The electron-transfer oxidation of these cuprates with benzil proceeds smoothly to produce the homo-coupled biaryls in moderate yields.
Pages: 162-165 | 1345 Views 117 Downloads
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How to cite this article:
M Jalilur Rahman, Manjur Alahy, Md. Abdul Malek, Sadia Jannat, Rehana Pervin, Shameem Ara Begum. Synthesis of biaryls through electron-transfer oxidation of Organo-Cuprates with Benzil. Int J Chem Stud 2017;5(2):162-165.
