International Journal of Chemical Studies
Vol. 3, Issue 2 (2015)
Author(s): Manmohan Krishna Upadhyaya
Abstract: Some of the key features that are present in these molybdoenzymes are as follows. These enzymes contain sulfur atoms as follows. These enzymes contain sulfur atoms as bidentate ligands, which are coordinated to metal centers. Most of the oxo-transfer molybdenum reagents contain dtatically demanding sulfur ligands, therby making them suitable models for molybdoenzymes. The literature survey indicates that dialkylidithiocarbamate complex of molybdenum (VI as well as IV) appears to posses these features. Several reagents such as molybdenum (VI) dioxobisdiethyldithiocarbamate (1, MoO2Et2NCS2)2), MoO2 (acac)2, sodium molybdate (Na2MaO4.2H2O) and ammonium molybdate [(NH4)6Mo7O24.4H2O] were also screened under a variety of reaction conditions.
Pages: 45-47 | 946 Views 15 Downloads
How to cite this article:
Manmohan Krishna Upadhyaya. Molybdenum reagents. Int J Chem Stud 2015;3(2):45-47.