International Journal of Chemical Studies
  • Printed Journal
  • Indexed Journal
  • Refereed Journal
  • Peer Reviewed Journal
P-ISSN: 2349-8528, E-ISSN: 2321-4902   |   Impact Factor: GIF: 0.565 NAAS Rating: 5.31 NEW

International Journal of Chemical Studies

Vol. 1, Issue 3 (2013)
Synthesis and Characterization of Antimony Carboxylates


Author(s): Charu Vatsa *, Amol S. Pawar and Shivram S. Garje

Abstract: The antimony tris carboxylate of the type, SbL3 ­was prepared by the reaction of antimony trichloride with sodium salt of furoic acid in 1:3 stoichiometry, whereas, antimony trichloride adduct, (SbCl3(LH)) (LH = furoic acid) was prepared by the reaction of antimony trichloride with furoic acid in 1:1 ratio. The complexes obtained were characterized by elemental analysis, IR and multinuclear (1H, 13C{1H}) NMR spectroscopic techniques. Based on spectroscopic data a ligand coordination through oxygen atoms of the carboxylate group has been suggested.

Related Graphics: Click here for more related graphics

1H NMR of furoic acid ligand in CDCl3
Fig. 1: 1H NMR of furoic acid ligand in CDCl3

1H NMR of SbL3 complex in dmso-d6
Fig. 2: 1H NMR of SbL3 complex in dmso-d6

1H NMR of SbCl3(LH) in dmso-d6
Fig. 3: 1H NMR of SbCl3(LH) in dmso-d6

Pages: 73-81  |  988 Views  8 Downloads

download (9699KB)
How to cite this article:
Charu Vatsa *, Amol S. Pawar, Shivram S. Garje. Synthesis and Characterization of Antimony Carboxylates. Int J Chem Stud 2013;1(3):73-81.
International Journal of Chemical Studies