Vol. 1, Issue 3 (2013)
Synthesis and Characterization of Antimony Carboxylates
Author(s): Charu Vatsa *, Amol S. Pawar and Shivram S. Garje
Abstract: The antimony tris carboxylate of the type, SbL3 Âwas prepared by the reaction of antimony trichloride with sodium salt of furoic acid in 1:3 stoichiometry, whereas, antimony trichloride adduct, (SbCl3(LH)) (LH = furoic acid) was prepared by the reaction of antimony trichloride with furoic acid in 1:1 ratio. The complexes obtained were characterized by elemental analysis, IR and multinuclear (1H, 13C{1H}) NMR spectroscopic techniques. Based on spectroscopic data a ligand coordination through oxygen atoms of the carboxylate group has been suggested.
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Fig. 1: 1H NMR of furoic acid ligand in CDCl3
Fig. 2: 1H NMR of SbL3 complex in dmso-d6
Fig. 3: 1H NMR of SbCl3(LH) in dmso-d6
Pages: 73-81 | 2042 Views 133 Downloads
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How to cite this article:
Charu Vatsa *, Amol S. Pawar, Shivram S. Garje. Synthesis and Characterization of Antimony Carboxylates. Int J Chem Stud 2013;1(3):73-81.
